RESUMO
We combine ultrafast pump-probe spectroscopy with optical trapping to study homogeneous damping of the acoustic vibrations of single gold nanospheres (80 nm diameter) and nanorods (25 nm diameter by 60 nm length) in water. We find a significant particle-to-particle variation in damping times. Our results indicate that vibrational damping occurs not only by dissipation into the liquid, but also by damping mechanisms intrinsic to the particle. Our experiment opens the study of mechanisms of intrinsic mechanical dissipation in metals at frequencies 1-1000 GHz, a range that has been difficult to access thus far.
Assuntos
Acústica , Ouro/química , Nanopartículas Metálicas/química , Água/química , Tamanho da Partícula , Análise Espectral , Propriedades de Superfície , VibraçãoRESUMO
We present the first acoustic vibration measurements of single gold nanorods with well-characterized dimensions and crystal structure. The nanorods have an average size of 90 nm x 30 nm and display two vibration modes, the breathing mode and the extensional mode. Correlation between the dimensions obtained from electron microscope images and the vibrational frequencies of the same particle allows us to determine the elastic moduli for each individual nanorod. Contrary to previous reports on ensembles of gold nanorods, we find that the single particle elastic moduli agree well with bulk values.
